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Kalichevsky, Vladimir A. (1924-01-01) Manufacturing of perchloric acid. http://resolver.caltech.edu/CaltechETD:etd-05052006-154839


Type of Document Senior Thesis
Author Kalichevsky, Vladimir A.
URN etd-05052006-154839
Persistent URL http://resolver.caltech.edu/CaltechETD:etd-05052006-154839
Title Manufacturing of perchloric acid
Degree Bachelor of Science
Option Chemical Engineering
Advisory Committee
Advisor Name Title
unknown Committee Chair
Keywords
  • none
Date of Defense 1924-01-01
Availability unrestricted
Abstract
The object of this research was to study quantitatively possibilities of a continuous process of production of perchloric acid from nitrogen peroxide and ammonium perchlorate. Perchloric acid has many properties which make it an important acid in industrial and analytical work and its use would be much greater if its cost of production could be lowered. It is a strong monobasic acid, stable in solutions (up to 60%), has a high boiling point. There are relatively few insoluble salts (potassium, rubidium, caesium, and thallium perchlorates are only highly soluble) and the difference in solubilities of potassium and sodium perchlorates give an easy method of separation of these two metals in analytical work.
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