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Jacob, Daniel James (1985-01-15) The origins of inorganic acidity in fogs. http://resolver.caltech.edu/CaltechETD:etd-01112005-133508


Type of Document Dissertation
Author Jacob, Daniel James
URN etd-01112005-133508
Persistent URL http://resolver.caltech.edu/CaltechETD:etd-01112005-133508
Title The origins of inorganic acidity in fogs
Degree PhD
Option Environmental Science and Engineering
Advisory Committee
Advisor Name Title
Michael R. Hoffman Committee Chair
F.H. Shair Committee Member
James J. Morgan Committee Member
John H. Seinfeld Committee Member
Keywords
  • None
Date of Defense 1985-01-15
Availability unrestricted
Abstract
A rotating arm device to collect large samples of fogwater for chemical analysis was designed and fully characterized. This instrument was used to determine the chemical composition of fogwater at a large number of sites in California. Fogwater at both urban and non-urban sites was frequently found to contain important inorganic acidity. Chemical models were developed to interpret the origins of this acidity in terms of aqueous-phase S(IV) oxidation reactions and acid/base titration processes in the fog and the precursor atmosphere. These models were found to succesfully interpret the inorganic acidity in fogwater and aerosol during wintertime stagnation episodes in the San Joaquin Valley of California.

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